We have developed a new cyclopropanation reaction from aliphatic nitro compounds on treatment with silver oide and iodine. Optically active cyclopropanes are recently prepared as well. A novel double carbon-carbon bond cleavage reaction was also observed.
Publications
Kamimura, A.; Kadowaki, A.; Yoshida, T.; Takeuchi, R.; Uno, H. Chem. Eur. J. 2009, 16, 10330-10334.
Kamimura, A.; Takeuchi, R.; Ikeda, K.; Moriyama, T.; Sumimoto, M. J. Org. Chem. 2012, 77, 2236 – 2245.
Kamimura, A.; Ikeda, K.; Moriyama, T.; Uno, H. Tetrahedron Lett. 2013, 54, 1842 – 1844: DOI: 10.1016/j.tetlet.2013.01.094.
Kamimura,A.; Moriyama, T.; Ito, Y.; Kawamoto, T.; Uno, H.
J. Org. Chem. 2016, 81, 4664 – 4681: DOI: 10.1021/acs.joc.6b00566.
