研究業績（論文・著書）
【2017】
上村明男
5. A Kinetic Study on the Conversion of Nylon 12 to Methyl 12-Hydroxydodecanoate in Supercritical MeOH in the presence of Carboxylic Acid, Akio Kamimura,* Kosuke Ikeda, Shuzo Suzuki, Kazunari Kato, Hiroshi Matsumoto, Kouji Kaiso and Makoto Yoshimoto, Polym. Degrad. Stab. 2017, 146, 95 – 104: doi.org/10.1016/j.polymdegradstab.2017.09.015.
4. An efficient and selective conversion of sorbitol in ionic liquids: use of ion exchange resin as a solid acid catalyst, Akio Kamimura,* Kengo Murata and Takuji Kawamoto, Tetrahedron Lett. 2017, 58, 3616-3618: DOI: 10.1016/j.tetlet.2017.07.105.
3. Preparation of 2,3-trans-substituted piperidines from optically active beta-amino-alpha-methylene esters: Synthesis of optically active (2S,3R)-(–)-epi-CP-99,994, Akio Kamimura,* Ryuichiro Yo, and Hidemitsu Uno, Tetrahedron 2017, 73, 4770-4778: DOI: 10.1016/j.tet.2017.06.054
2. Synthesis of alpha-Trifluoromethylated Ketones from Vinyl Triflates in the Absence of External Trifluoromethyl Sources, Takuji Kawamoto,* Rio Sasaki, and Akio Kamimura, Angew. Chem. Int. Ed. 2017, 56, 1342-1345: DOI: 10.1002/ange.201608591
- Highlighted in Synfacts, 2017, 1. DOI: 10.1055/s-0036-1589791
1. Efficient depolymerization and chemical conversion of polyamide 66; useful conversion to 1,6-hexanediol
Hiroshi Matsumoto, Yugo Akinari, Kouji Kaiso and Akio Kamimura*
J. Mater. Cycles Waste Manag. 2017, 19, 326 - 331:
DOI: 10.1007/s10163-015-0425-4.
西形孝司
8. Copper-catalyzed Amination of Congested and Functionalized α-Bromocarboxamides with Amines or Ammonia at Room Temperature, S. Ishida, K. Takeuchi, N. Taniyama, Y. Sunada, T. Nishikata*
Angew. Chem., Int. Ed. 2017, accepted. DOI: 10.1002/anie.201706293.
7. Copper-catalyzed reductive borylations on water, C. Tanaka, K. Nakamura, T. Nishikata*
Tetrahedron 2017, 73, 3999.
6. Amine-controlled Divergent Reaction: Iminolactonization and Olefination in the presence of a Cu(I) catalyst, T. Nishikata*, K. Itonaga, N. Yamaguchi
Org. Lett. 2017, 19, 2686.
5.Highly Efficient Cu Catalyst System for the Radical Reactions of α-Bromocarbonyls, Y. Noda, T. Nishikata*
Chem. Commun. 2017, 53, 5017.
4. Exchanging alkyl groups via unstrained C-C bond cleavage in the presence of a copper catalyst, M. Wada, Y. Noda, T. Nishikata*
Chem. Asian J. 2017, 12, 978.
3. A ligand containing five nitrogen atoms enabled efficient homocyclization of alpha-bromocarbonyl amides in the presence of a copper catalyst, N. Miwa, Y. Yamane, T. Nishikata*
Chem. Lett. 2017, 46, 563.
2. Dichloromethane as a Chlorination Reagent for α-Bromocarbonyl Compounds in the Presence of a Copper Catalyst, K.Takeuchi, S. Ishida, T. Nishikata*
Chem. Lett. 2017, 46, 644.
1. Tandem reactions enable trans- and cis-hydro-tertiary-alkylations catalyzed by a copper salt, K. Nakamura, T. Nishikata*
ACS Catal., 2017, 7, 1049.
- Highlighted in Synfacts 2017, 13, 496.
上條真
1. Synthesis of Alkylated Pyrimidines via Photoinduced Coupling Using Benzophenone as a Mediator
Shin Kamijo, Kaori Kamijo, and Toshihiro Murafuji
J. Org. Chem. 2017, 82, 2664-2671: DOI: 10.1021/acs.joc.6b03058.
村藤俊宏
1. Synthesis of Alkylated Pyrimidines via Photoinduced Coupling Using Benzophenone as a Mediator
Shin Kamijo, Kaori Kamijo, and Toshihiro Murafuji
J. Org. Chem. 2017, 82, ASAP: DOI: 10.1021/acs.joc.6b03058.
川本拓治
3. N-Heterocyclic Carbene Boryl Iodides Catalyze Insertion Reactions of N-Heterocyclic Carbene Boranes and Diazoesters, Thomas H. Allen, Takuji Kawamoto, Sean Gardner, Steven J. Geib, and Dennis P. Curran*, Org. Lett. 2017, 19, 3680–3683. doi:10.1021/acs.orglett.7b01777.2016.
2. An efficient and selective conversion of sorbitol in ionic liquids: use of ion exchange resin as a solid acid catalyst, Akio Kamimura,* Kengo Murata and Takuji Kawamoto, Tetrahedron Lett. 2017, 58, accepted: DOI: 10.1016/j.tetlet.2017.07.105.
1. Synthesis of a-Trifluoromethylated Ketones from Vinyl Triflates in the Absence of External Trifluoromethyl Sources, Takuji Kawamoto,* Rio Sasaki, and Akio Kamimura, Angew. Chem. Int. Ed. 2017, 56, 1342-1345: DOI: 10.1002/ange.201608591
-
-Highlighted in Synfacts, 2017, 1. DOI: 10.1055/s-0036-1589791
受賞：平成29年度有機合成化学協会九州山口支部・優秀論文賞
【2016年】
上村明男
9. Regioselective Double Stille Coupling Reaction of Bicyclic Stannolanes
Akio Kamimura,* Toshiyuki Tanaka, Masahiro So, Tomoyuki Itaya, Kantaro Matsuda and Takuji Kawamoto
Org. Biomol. Chem. 2016, 14, 8109 – 8122:
DOI: 10.1039/C6OB01018K.
8. Oxidative synthesis of isoxazoline-N-oxide from optically active nitro alcohols
Takaaki Moriyama, Takuji Kawamoto, Hidemitsu Uno, and Akio Kamimura*
Heterocycles 2016, 92, 1479 – 1489: DOI: 10.3987/COM-16-13497
7. Modulation of cellulase activity by charged lipid bilayers with different acyl chain properties for efficient hydrolysis of ionic liquid-pretreated cellulose
Kai Mihono, Takeshi Ohtsu, Mai Ohtani, Makoto Yoshimoto,* Akio Kamimura
Colloids Surface B 2016, 146, 198 – 203:
doi:10.1016/j.colsurfb.2016.06.005
6. An oxidative cyclopropanation reaction of primary nitro compounds using Fe2O3
Takaaki Moriyama, Yuji Ito, Yusuke Koyama, Takuji Kawamoto, and Akio Kamimura*
Tetrahedron Lett. 2016, 57, 3127 – 3128: DOI: 10.1016/j.tetlet.2016.06.013.
5. A radical cascade reaction of aza-1,6-enyne compounds using allyltributyltin
Akio Kamimura,* Koichiro Miyazaki, Takuji Kawamoto, Hidemitsu Uno
Tetrahedron 2016, 72, ASAP: DOI: 10.1016/j.tet.2016.04.078
4. An expedient access to 6-arylpyridin-3-ols via oxidative rearrangement of 5-arylfurfurylamines
Michael C. D. Fürst, Caroline Sauer, Takaaki Moriyama, Akio Kamimura, and Markus R. Heinrich*
Eur. J. Org. Chem. 2016, early view: DOI: 10.1002/ejoc.2016003777
3. Asymmetric Synthesis of Bicyclic Nitrocyclopropanes from Primary Nitro Compounds and Stereoselective Formation of Tetrahydro-2H-cyclopenta[b]furans via Ring Expansion/Cyclization Reaction
Akio Kamimura,* Takaaki Moriyama, Yuji Ito, Takuji Kawamoto, and Hidemitsu Uno
J. Org. Chem. 2016, 81, 4664−4681: DOI: 10.1021/acs.joc.6b00566
2. An Efficient Conversion of Lysine to 2-Aminocaprolactam
Hiroshi Matsumoto, Kouji Kaiso, and Akio Kamimura*
Heterocycles 2016, 92, 337 – 345.
1. A radical cascade reaction triggered by thiyl radical; an approach toward synthesis of tricyclic structure of platensimycin
Akio Kamimura* and Yusuke Kawakami
Phosphous, Sulfur Silicon Relat. Elem. 2016, 191, 259 – 262:
DOI:10.1080/10426507.2015.1064922
西形孝司
2. Different behaviors of a Cu catalyst in amine solvents: Controlling N and O reactivities of amide
Yamane, Y.; Miyazaki, K.; Nishikata, T.
ACS Catal. 2016, accepted: DOI: 10.1021/acscatal.6b02309.
1. Site-selective tertiary-alkyl–fluorine bond formation from alpha-bromoamides using a copper–CsF catalyst system
Nishikata, T.; Ishida, S.; Fujimoto, R.
Angew. Chem., Int. Ed. 2016, 55, 10008–10012.
-
-Selected in Insideback Cover
Award
日本化学会 第３０回若い世代の特別講演証
有機合成化学協会東ソー研究企画賞
上條真
6. Aryl Ketone Catalyzed Radical Allylation of C(sp3)–H Bonds under Photoirradiation
Shin Kamijo, Kaori Kamijo, Kiyotaka Maruoka, and Toshihiro Murafuji
Org. Lett. 2016, 18, 6516–6519: DOI: 10.1021/acs.orglett.6b03586
5. Blue Amino Acids Derived from 1-Azulenyl Boronic Acid Pinacol Ester via the Petasis Reaction, Toshihiro Murafuji*, Yusuke Tasaki, Masayuki Fujinaga, Keisuke Tao, Shin Kamijo and Katsuya Ishiguro, Synthesis, 2016, in press
4. Alkylation of Nonacidic C(sp3)–H Bonds by Photoinduced Catalytic Michael-Type Radical Addition
Kamijo, S.; Takao, G.; Kamijo, K.; Tsuno, T.; Ishiguro, K.; Murafuji, T.
Org. Lett. 2016, 4912–4915: DOI: 10.1021/acs.orglett.6b02391.
3. Photo-induced Substitutive Introduction of the Aldoxime Functional Group to Carbon Chains: A Formal Formylation of Non-Acidic C(sp3)–H Bonds
Kamijo, S.*; Takao, G.; Kamijo, K.; Hirota, M.; Tao, K.; Murafuji, T.
Angew. Chem. Int. Ed. 2016, 55, 9695–9699.
2. Two-directional carbon chain elongation via the consecutive 1,4-addition of allyl malononitrile and the Cope rearrangement on an alkynoate platform
Kamijo, S.*; Kamijo, K.; Magarifuchi, D.; Ozawa, R.; Tao, K.; Murafuji, T.
Tetrahedron Lett. 2016, 57, 137–140.
1. Synthesis of Aliphatic Azides by Photoinduced C(sp3)–H Azidation
Kamijo, S.*; Watanabe, M.; Kamijo, K.; Tao, K.; Murafuji, T.
Synthesis 2016, 48, 115–121.
村藤俊宏
6. Aryl Ketone Catalyzed Radical Allylation of C(sp3)–H Bonds under Photoirradiation
Shin Kamijo, Kaori Kamijo, Kiyotaka Maruoka, and Toshihiro Murafuji
Org. Lett. 2016, 18, 6516–6519: DOI: 10.1021/acs.orglett.6b03586
5. Blue Amino Acids Derived from 1-Azulenyl Boronic Acid Pinacol Ester via the Petasis Reaction, Toshihiro Murafuji*, Yusuke Tasaki, Masayuki Fujinaga, Keisuke Tao, Shin Kamijo and Katsuya Ishiguro, Synthesis, 2016, in press
4. Alkylation of Nonacidic C(sp3)–H Bonds by Photoinduced Catalytic Michael-Type Radical Addition
Kamijo, S.; Takao, G.; Kamijo, K.; Tsuno, T.; Ishiguro, K.; Murafuji, T.
Org. Lett. 2016, 4912–4915: DOI: 10.1021/acs.orglett.6b02391.
3. Photo-induced Substitutive Introduction of the Aldoxime Functional Group to Carbon Chains: A Formal Formylation of Non-Acidic C(sp3)–H Bonds
Kamijo, S.*; Takao, G.; Kamijo, K.; Hirota, M.; Tao, K.; Murafuji, T.
Angew. Chem. Int. Ed. 2016, 55, 9695–9699.
2. Two-directional carbon chain elongation via the consecutive 1,4-addition of allyl malononitrile and the Cope rearrangement on an alkynoate platform
Kamijo, S.*; Kamijo, K.; Magarifuchi, D.; Ozawa, R.; Tao, K.; Murafuji, T.
Tetrahedron Lett. 2016, 57, 137–140.
1. Synthesis of Aliphatic Azides by Photoinduced C(sp3)–H Azidation
Kamijo, S.*; Watanabe, M.; Kamijo, K.; Tao, K.; Murafuji, T.
Synthesis 2016, 48, 115–121.
川本拓治
5. Regioselective Double Stille Coupling Reaction of Bicyclic Stannolanes
Akio Kamimura,* Toshiyuki Tanaka, Masahiro So, Tomoyuki Itaya, Kantaro Matsuda and Takuji Kawamoto
Org. Biomol. Chem. 2016, 14, 8109 – 8122:
DOI: 10.1039/C6OB01018K.
4. Oxidative synthesis of isoxazoline-N-oxide from optically active nitro alcohols
Takaaki Moriyama, Takuji Kawamoto, Hidemitsu Uno, and Akio Kamimura*
Heterocycles 2016, 92, 1479 – 1489: DOI: 10.3987/COM-16-13497
3. An oxidative cyclopropanation reaction of primary nitro compounds using Fe2O3
Takaaki Moriyama, Yuji Ito, Yusuke Koyama, Takuji Kawamoto, and Akio Kamimura*
Tetrahedron Lett. 2016, 57, 3127 – 3128: DOI: 10.1016/j.tetlet.2016.06.013.
2. A radical cascade reaction of aza-1,6-enyne compounds using allyltributyltin
Akio Kamimura,* Koichiro Miyazaki, Takuji Kawamoto, Hidemitsu Uno
Tetrahedron 2016, 72, ASAP: DOI: 10.1016/j.tet.2016.04.078
1. Asymmetric Synthesis of Bicyclic Nitrocyclopropanes from Primary Nitro Compounds and Stereoselective Formation of Tetrahydro-2H-cyclopenta[b]furans via Ring Expansion/Cyclization Reaction
Akio Kamimura,* Takaaki Moriyama, Yuji Ito, Takuji Kawamoto, and Hidemitsu Uno
J. Org. Chem. 2016, 81, 4664−4681: DOI: 10.1021/acs.joc.6b00566.
【2015年】
上村明男
3. A mechanistic study on SHi reaction at tin atoms in a radical cascade reaction
Akio Kamimura,* Tatsuro Yoshinaga, Fumiaki Noguchi, Koichiro Miyazaki and Hidemitsu Uno
Org. Chem. Front. 2015, 2, 713 - 720: DOI: 10.1039/C5QO00063G.
2. Synthesis of unsymmetrical 3,7-bisarylthio-2,8-dioxydibenzofuran and its physical properties
Akio Kamimura,* Mari Ishikawa, Ryusuke Watanabe, Sanshiro Sakamoto, and Hidemitsu Uno
Phosphous, Sulfur Silicon Relat. Elem. 2015, 190, 1219-1224:
DOI:10.1080/10426507.2014.983598
1. Synthesis of dibenzo[c,e][1,2]diazocines - a new group of eight-membered cyclic azo compounds
Tomomi Nokubi, Stephanie Kindt, Tim Clark, Akio Kamimura, Markus R. Heinrich
Tetrahedron Lett. 2015, 56, 316 - 320: doi:10.1016/j.tetlet.2014.11.064.
西形孝司
3. Shingo Ishikawa, Yushi Noda, Masaru Wada, Takashi Nishikata*
A copper-catalyzed Formal [3+2]-cycloaddition for the synthesis of all different aryl-substituted furans and thiophenes
J. Org. Chem. 2015, 80, 7555-7563: DOI: 10.1021/acs.joc.5b01139.
2. A facile formal [2+1] cycloaddition of styrenes with alpha-bromocarbonyls catalyzed by copper: efficient synthesis of donor-acceptor cyclopropanes
Takashi Nishikata,* Yushi Noda, Ryo Fujimoto, Shingo Ishikawa
Chem. Commun. 2015, 51, 12843-12846.
1. A detachable ester bond enables perfect Z-alkylation of olefins for the synthesis of tri- and tetrasubstituted alkenes
Takashi Nishikata,* Kimiaki Nakamura, Yuki Inoue, Shingo Ishikawa
Chem. Commun. 2015, 51, 10154-10157.
上條真
2. Photoinduced Oxidation of Secondary Alcohols Using 4-Benzoylpyridine as an Oxidant
Kamijo, S.*; Tao, K.; Takao, G.; Tonoda, H.: Murafuji, T.
Org. Lett. 2015, 17, 3326–3329.
1. Ether derivatization via two-step protocol comprised of photochemical ethereal C–H chlorination and nucleophilic substitution
Kamijo, S.*; Tao, K.; Takao, G.; Murooka, H.; Murafuji, T.
Tetrahedron Lett. 2015, 56, 1904–1907.
受賞
Thieme Chemistry Journal Award 2015
村藤俊宏
3. Synthesis and acid-base properties of a proton-bridged biaryl compound based on pyridylazulene
Kazuki Ninomiya, Yumi Harada, TomoakinKanetou, Yuma Suenaga, Toshihiro Murafuji* and Ryo Tsunashima*
New J. Chem. 2015, 39, 9079-9085.
- Selected in Front Cover
2. Photoinduced Oxidation of Secondary Alcohols Using 4-Benzoylpyridine as an Oxidant
Kamijo, S.*; Tao, K.; Takao, G.; Tonoda, H.: Murafuji, T.
Org. Lett. 2015, 17, 3326–3329.
1. Ether derivatization via two-step protocol comprised of photochemical ethereal C–H chlorination and nucleophilic substitution
Kamijo, S.*; Tao, K.; Takao, G.; Murooka, H.; Murafuji, T.
Tetrahedron Lett. 2015, 56, 1904–1907.
川本拓治
4. Photoinduced Aminocarbonylation of Aryl Iodides
Takuji Kawamoto, Aoi Sato, and Ilhyong Ryu*
Chem. Eur. J. 2015, 21, 14764–14767. DOI: 10.1002/chem.201503164
Selected as Hot Paper.
- Highlighted in Chemistry Views Magazine.
3. Synthesis of 1,3-Dialkylimidazol-2-ylidene Boranes from 1,3-Dialkylimidazolium Iodides and Sodium Borohydride
Sean Gardner, Takuji Kawamoto, and Dennis P. Curran*
J. Org. Chem. 2015, 80, 9794–9797. DOI: 10.1021/acs.joc.5b01682
2. 1,3-Dimethylimidazoyl-2-ylidene borane
Sean Gardner, Takuji Kawamoto and Dennis P. Curran*
Org. Synth. 2015, 92, 342–355. DOI: 10.15227/orgsyn.092.0342
1. Radical Reactions of N‐Heterocyclic Carbene Boranes with Organic Nitriles: Cyanation of NHC-Boranes and Reductive Decyanation of Malononitriles
Takuji Kawamoto, Steven J. Geib, and Dennis P. Curran*
J. Am. Chem. Soc. 2015, 137, 8617–8622.
【2014年】
上村明男
【論文】
7. A Rapid Conversion of Sorbitol to Isosorbide in Hydrophobic Ionic Liquids under Microwave Irradiation
Akio Kamimura,* Kengo Murata, Yoshiki Tanaka, Tomoki Okagawa, Hiroshi Matsumoto, Kouji Kaiso, and Makoto Yoshimoto
ChemSusChem 2014, 7, 3257 – 3259: DOI: 10.1002/cssc.201402655
6. Preparation of 2,3-Dihydrofurans via a Double Allylic Substitution Reaction of Allylic Nitro Compounds
Toshiki Nakano, Koichiro Miyazaki and Akio Kamimura*
J. Org. Chem. 2014, 79, 8103 – 8109: DOI: 10.1021/jo5013042
5. Gold(I) Catalyzed Synthesis of Optically Active 1,4-Oxazepan-7-ones
Akio Kamimura,* Yu Yamane, Ryuichiro Yo, Toshiyuki Tanaka, and Hidemitsu Uno
J. Org. Chem. 2014, 79, 7696 – 7702: DOI: 10.1021/jo501254x
4. Efficient conversion of polyamides to omega-hydroxyalkanoic acids; a new method for chemical recycling of waste plastics
Akio Kamimura,* Kosuke Ikeda, Shuzo Suzuki, Kazunari Kato, Yugo Akinari, Tsunemi Sugimoto, Kohichi Kashiwagi, Kouji Kaiso, Hiroshi Matsumoto, and Makoto Yoshimoto
ChemSusChem 2014, 7, 2473 – 2477: DOI: 10.1002/cssc.201402125
3. 不斉Aza-Morita-Baylis-Hillman等価反応を用いた複素環の合成
上村明男・石川慎吾
有機合成化学協会誌, 2014, 72, 929 – 939
2. Preparation of Hydrophobic 2-Phenylthiohydroquinone Dimers and Evaluation of Their Photophysical Properties
Akio Kamimura,* Yasuko Takechi, and Ryusuke Watanabe
Heteroatom Chem. 2014, 25, 402 – 409.
1. 4,4'-Disulfanyl-2,2',5,5'-tetraoxybiaryl Derivatives as a Water Soluble Fluorescent Dye
Akio Kamimura, Tomomi Nokubi, Ryusuke Watanabe, Mari Ishikawa, Kotaro Nasu, Hidemitsu Uno, and Michinori Sumimoto
J. Org. Chem. 2014, 79, 1068 – 1083. DOI: 10.1021/jo402522y.
【著書】
4. The 8th Choshu-London Symposium in Organic Chemistry
Ed. by J. Anderson, A. Kamimura, Yamaguchi University. (1/December/2014).
3. 第41回有機典型元素化学討論会講演要旨集 上村明男編集, 2014年11月27日.
2. [2 + 1]-type cyclopropanation reactions, in Methods and applications of cycloaddition reactions in organic syntheses, Ed. by Nagatoshi Nishiwaki, John Wiley and Sons, New Jersey, 2014 (pp 1 - 66).
1. The 7th Choshu-London Symposium in Organic Chemistry
Ed. by J. Anderson, W. B. Motherwell, A. Kamimura, UCL. (12/March/2014)
西形孝司
1. General and Facile Method for exo-Methlyene Synthesis via Regioselective C–C Double-Bond Formation Using a Copper–Amine Catalyst System
Takashi Nishikata,* Kimiaki Nakamura, Kohei Itonaga, and Shingo Ishikawa
Org. Lett. 2014, 16, 5816–5819. DOI: 10.1021/ol502953w.
上條真
2. Photoinduced sulfonylation of cyclic ethers
Kamijo, S.*; Hirota, M.; Tao, K.; Watanabe, M.; Murafuji, T.
Tetrahedron Lett. 2014, 55, 5551–5554.
1. Photochemically Induced Radical Alkenylation of C(sp3)–H Bonds
Amaoka, Y.; Nagatomo, M.; Watanabe, M.; Tao, K.; Kamijo, S.*; Inoue, M.*
Chem. Sci. 2014, 5, 4339–4353.
村藤俊宏
2. Activity of Antifungal Organobismuth(III) Compounds Derived from Alkyl Aryl Ketones against S. cerevisiae: Comparison with a Heterocyclic Bismuth Scaffold Consisting of a Diphenyl Sulfone
Toshihiro Murafuji,* Mai Tomura, Katsuya Ishiguro, Isamu Miyakawa
Molecules 2014, 19, 11077-11095 (Special issue Heterocyclic and Medicinal Chemistry).
1. Photoinduced sulfonylation of cyclic ethers
Kamijo, S.*; Hirota, M.; Tao, K.; Watanabe, M.; Murafuji, T.
Tetrahedron Lett. 2014, 55, 5551–5554.
川本拓治
1. A Theoretical Study for Reduction of Acyl Radicals with Borohydride Anions, Kawamoto, T.; Matsubara, H.; Ryu, I.
Chem. Lett. 2014, 43, 1140-1142. Selected as Editor’s Choice.
2. Borohydride-Mediated Radical Addition Reactions of Organic Iodides to Electron-Deficient Alkenes, Kawamoto, T.; Uehara, S.; Hirao, H.; Fukuyama, T.; Matsubara, H.; Ryu, I.
J. Org. Chem. 2014, 79, 3999-4007.
3. Cyanoborohydride-Promoted Radical Arylation of Benzene, Kawamoto, T.; Sato, A.; Ryu, I.
Org. Lett. 2014, 16, 2111-2113.
4. Radical Reactions of Borohydrides, Kawamoto, T.; Ryu, I.
Org. Biomol. Chem. 2014, 12, 9733-9742.- Selected as inside front cover.
5. カルボニル化の新手法, 川本 拓治, 福山 高英, 柳 日馨
有機合成化学協会誌, 2014, 72, 493-505 (in Japanese).
【2013年】
上村明男
【論文】
11. A Rapid Route to Aminocyclopropanes via Carbamatoorganozinc Carbenoids
Shingo Ishikawa, Tom D. Sheppard, Jarryl M. D'Oyley, Akio Kamimura and William B.
Motherwell*
Angew. Chem. Int. Ed. 2013, 52, 10060 – 10063: DOI: 10.1002/anie.201304720.
10. A Radical Cascade Cyclization to Prepare Dihydrothiophenes Induced by Thiyl
Radicals as Sulfur Biradical Equivalents
Akio Kamimura*, Koichiro Miyazaki, Yu Yamane, Ryuichiro Yo, Shingo Ishikawa,
Hidemitsu Uno, and Michinori Sumimoto
J. Org. Chem. 2013, 78, 7816 – 7822: DOI: 10.1021/jo400975t.
9. Preparation of optically active bicyclodihydrosiloles by radical cascade reaction
Koichiro Miyazaki, Yu Yamane, Ryuichiro Yo, Hidemitsu Uno, and Akio Kamimura*
Beilstein J. Org. Chem. 2013, 9, 1326 – 1332; doi:10.3762/bjoc.9.149.
8. Hydrolysis of Insoluble Cellulose to Glucose Catalyzed by Cellulase-Containing Liposomes in an Aqueous Solution of 1-Butyl-3-Methylimidazolium Chloride
Makoto Yoshimoto*, Kazuhiko Tanimura, Kazuki Tokunaga, and Akio Kamimura
Biotechnol. Progr. 2013, 29, 1190 – 1196: DOI: 10.1002/btpr.1779.
7. Sub-stoichiometric oxidation of benzylic alcohols with commercially available activated MnO2 under oxygen atmosphere; a green modification of the benzylic oxidation
Akio Kamimura,* Hiroyuki Komatsu, Takaaki Moriyama, and Yuichiro Nozaki
Tetrahedron 2013, 69, 5968 – 5962; DOI: 10.1016/j.tet.2013.04.109.
6. A New Water-soluble Fluorescent Dye Based on 2-Sulfanyl-1,4-dihydroquinone Dimers
Tomomi Nokubi, Kotaro Nasu, Ryusuke Watanebe, and Akio Kamimura*
Chem. Lett. 2013, 42, 876-878 ; DOI:10.1246/cl.130348.
5. Kinetic Study of the 7-endo Selective Radical Cyclization of N-tert-Butyl-o-bromobenzylmethacryl Amides: Kinetic Investigation of the Cyclization and 1,7-Hydrogen Transfer of Aromatic Radicals
Akio Kamimura,* Tomoko Kotake, Yuriko Ishihara, Masahiro So, and Takahiro Hayashi
J. Org. Chem. 2013, 78, 3961-3971: DOI: 10.1021/jo400326b.
4. Pd-catalyzed Tandem sp2-sp3 Coupling Reactions of Chiral Stannolanes: an Efficient
Preparation of Optically Active Tetrahydrobenz[f]isoindoles
Akio Kamimura,* Masahiro So, Shingo Ishikawa, and Hidemitsu Uno
Org. Lett. 2013, 15, 1402-1405: DOI: 10.1021/ol4003948.
3. Unexpected reductive double carbon-carbon bonds cleavage of bicyclic nitrocyclopropanes
Akio Kamimura,* Kosuke Ikeda, Takaaki Moriyama, and Hidemitsu Uno
Tetrahedron Lett. 2013, 54, 1842-1844: DOI: 10.1016/j.tetlet.2013.01.094.
2. Preparation of optically active 4-aminopyrrolidines by radical addition/cyclization to chiral N-(2-(methoxyimino)ethyl)-β-amino-α-methylene esters
Akio Kamimura,* Yu Yamane, and Hidemisu Uno
Phosphous, Sulfur Silicon Relat. Elem. 2013, 188, 356 – 366
DOI: 10.1080/10426507.2012.736893.
1. Oxidation of benzyl alcohols by semi-stoichiometric amounts of cobalt-doped birnessite-type layered MnO2 under oxygen atomosphere
Akio Kamimura,* Yuichiro Nozaki, Mai Nishiyama and Masaharu Nakayama
RSC Adv. 2013, 3, 468 – 472; DOI:10.1039/C2RA22117A
【著書】
2.イオン液体とマイクロ波照射によるプラスチックの解重合, 新しい溶媒を使った有機合成、分担執筆、S&T出版、東京、2013
1. 6th Choshu-London Memorial Symposium in Organic Chemistry
Ed. by A. Kamimura, Yamaguchi University. (17/January/2013)
西形孝司
【論文】
1. An Efficient Generation of a Functionalized Tertiary-Alkyl Radical for Copper-catalyzed Tertiary-Alkylative Mizoroki-Heck type Reaction
Takashi Nishikata*, Yushi Noda, Ryo Fujimoto, and Tomomi Sakashita
J. Am. Chem. Soc. 2013, 135, 16372 – 16375. DOI: 10.1021/ja409661n
【著書】
1. 1st American-Japanese Chemical Society Meeting in Yamaguchi University
Ed. by T. Nishikata, Yamaguchi University. (21/November/2013)
上條真
2. Photoinduced Direct Cyanation of C(sp3)-H Bonds
Tamaki Hoshikawa, Shun Yoshioka, Shin Kamijo, Masayuki Inoue*
Synthesis 2013, 45, 874-887.
1. Photochemically induced radical alkynylation of C(sp3)–H bonds
Tamaki Hoshikawa, Shin Kamijo and Masayuki Inoue*
Org. Biomol. Chem. 2013, 11, 164-169; DOI: 10.1039/C2OB26785C
村藤俊宏
2. メタル化反応による置換アズレン類の簡便合成
(Convenient Synthesis of Substituted Azulenes Based on Metalation)
Toshihiro Murafuji
有機合成化学協会誌 2013, 71, 217 – 228.
1. Heterocyclic bismuth carboxylates based on a diphenyl sulfone scaffold: Synthesis and antifungal activity against Saccharomyces cerevisiae
Toshihiro Murafuji*, Kunito Kitagawa, Daisuke Yoshimatsu, Kei Kondo, Katsuya Ishiguro, Ryo Tsunashima, Isamu Miyakawa, and Yuji Mikata
Eur. J. Med. Chem. 2013, 63, 531-535.
川本拓治
2. Flow Giese Reaction Using Cyanoborohydride as a Radical Mediator, Fukuyama, T.; Kawamoto, T.; Kobayashi, M.; Ryu, I.
Beilstein J. Org. Chem. 2013, 9, 1791-1796.
1. Efficient Hydroxymethylation Reactions of Iodoarenes Using CO and 1,3-Dimethylimidazol-2-ylidene Borane,
Kawamoto, T.; Okada, T.; Curran, D. P.; Ryu, I.
Org. Lett. 2013, 15, 2144-2147.
【2012年】
上村明男
【論文】
10. A study on the relationship between twisted pi-conjugate system for 1,5-diaryl-1,5-diazapentadienes and their photophysical properties
Akio Kamimura,* Hideki Matsu, Hiroyuki Suzukawa, Eisuke Sato, Michinori Sumimoto, and Hidemitsu Uno
Chem. Lett. 2012, 41, 984-986
9. Nylon 6 Depolymerization in Supercritical Alcohols Studied by the QM/MC/FEP Method
Thanayuth Kaweetirawatt, Toru Yamaguchi, Shota Hayashiyama, Michinori Sumimoto, Akio Kamimura and Kenji Hori
RSC Adv. 2012, 2, 8402-8409, DOI: 10.1039/C2RA20835K
8. Combination use of hydrophobic ionic liquids and LiCl as a good reaction system for the chemical conversion of cellulose to glucose
Akio Kamimura,* Tomoki Okagawa, Natsumi Oyama, Tamami Otsuka and Makoto Yoshimoto
Green Chem. 2012, 14, 2816-2820, DOI:10.1039/C2GC35811E
7. Facile Synthesis of Quinone Dimer Derivatives Substituted with Sulfanyl Groups and Their Properties
Akio Kamimura,* Tomomi Nokubi, Kotaro Nasu, Yasuko Takechi, Yuriko Ishihara, Kazunari Kato, Saori Noguchi, Masanori Watanabe, Masashi Shirai, Michinori Sumimoto, and Hidemitsu Uno
Chem. Lett. 2012, 41, 950-951
6. Unexpected formation of stannolanes and trigonal bipyramidal tin complexes by radical cyclization reaction
Akio Kamimura,* Shingo Ishikawa, Fumiaki Noguchi, Takaaki Moriyama, Masahiro So, Toshihiro Murafuji, and Hidemitsu Uno
Chem. Commun. 2012, 47, 6592 -6594
5. Preparation of SRN1-Type coupling Adducts from Aliphatic gem-Dinitro Compounds in Ionic Liquids
Akio Kamimura* and Seiichi Toyoshima
Molecules 2012, 17, 4782 - 4790
4. Total synthesis of ent-calystegine B4 via nitro-Michael/aldol reaction
Akio Kamimura,* Koichiro Miyazaki, Shuzo Suzuki, Shingo Ishikawa and Hidemitsu Uno
Org. Biomol. Chem. 2012, 10, 4362 - 4366
3. Concise Synthesis of 2-Benzazepine Derivatives and Their Biological Activity
Masahiro So, Tomoko Kotake, Kenji Matsuura, Makoto Inui,* and Akio Kamimura*
J. Org. Chem. 2012, 77, 4017 - 4028.
2. Heck–Matsuda Reaction for Allylic Nitro Compounds; A Short-step Asymmetric Synthesis of FTY720 Derivatives
Toshiki Nakano, Mizuki Miyahara, Toshiyuki Itoh,* and Akio Kamimura*
Eur. J. Org. Chem. 2012, 2161 – 2166
1. Stereoselective Synthesis of 1-Nitrobicyclo[3.1.0]hexanes and Fused Isoxazoline-N-oxides from Primary Nitro Compounds
Akio Kamimura,* Ryota Takeuchi, Kosuke Ikeda, Takaaki Moriyama, and Michinori Sumimoto
J. Org. Chem. 2012, 77, 2236 – 2245
【著書(いずれも分担執筆）】
「最先端材料システムOne Point2 イオン液体」高分子学会編集 分担執筆（共立出版）
「イオン液体の科学-新世代液体への挑戦-」イオン液体研究会 監督 西川恵子・大内幸雄・伊藤敏幸・大野弘幸・渡邊正義 編 分担執筆（丸善出版）
西形孝司
3. Hydrophobicity / Hydrophilicity Tunable Hyperbranched Polystyrenes As Novel Supports for Transition Metal Nanoparticles
Keisuke Kojima, Katsumi Chikama, Makoto Ishikawa, Akihiro Tanaka, Takashi Nishikata, Hironori Tsutsumi, Kazunobu Igawa, Hideo Nagashima*
Chem. Chommun. 2012, 48, 10666-10668
2. N-Alkylation of Tosylamides Using Esters as Primary- and Tertiary-Alkyl Sources Mediated by Hydrosilanes Activated by a Ruthenium Catalyst
Takashi Nishikata, Hideo Nagashima,
Angew. Chem., Int. Ed. 2012, 51, 5363-5366
1. Vinyl polymerization versus [1,3] O to C rearrangement in the ruthenium-catalyzed reactions of vinyl ethers with hydrosilanes
Nariaki Harada, Takashi Nishikata, and Hideo Nagashima,
Tetrahedron 2012, 68, 3243-325
上條真
【論文】
5. 直接的C–H官能基化反応の新展開:酸化と炭素ユニット導入
上條真
有機合成化学協会誌, 2012, 70, 996–1010.
4. Radical Amination of C(sp3)–H Bonds Using N-Hydroxyphthalimide and Dialkyl Azodicarboxylate
Amaoka, Y; Kamijo, S.; Hoshikawa, T.; Inoue, M.*
J. Org. Chem. 2012, 77, 9959–9969.
3. Microwave-assisted atom transfer radical addition of polychlorinated compounds to olefins without addition of metal catalysts
Kamijo, S.; Matsumura, S.; Inoue, M.*
Tetrahedron Lett. 2012, 53, 4368–7371.
2. Carbocyanation of trisubstituted olefins via Cu-catalyzed atom transfer radical addition
Kamijo, S.; Yokosaka, S.; Inoue, M.*
Tetrahedron Lett. 2012, 53, 4324–4327.
1. Attachment of carbonyl functionalities onto olefins via copper-promoted radical reaction of dichloromethylcyanides
Kamijo, S.; Yokosaka, S.; Inoue, M.*
Tetrahedron 2012, 68, 5290–5296.
【解説記事】
1. 炭素鎖末端をピンポイント酸化 基質自らが反応を制御する
上條真
化学 2012, 67, 66–67. (注目の論文)
村藤俊宏
3. Synthesis of benzotropone-annulated 1-azaazulenes and related compounds by Suzuki-Miyaura coupling/ aldol condensation cascade reaction and evaluations od their cytotoxic activity against HeLa S3 cells
Makoto Nakatani, Hiroyuki Fujii, Toshihiro Murafuji, Takahiro Gunji, Reiko Ikeda, Takeo Konakahara, Noritaka Abe*
Heterocycles 2012, 84, 461-472
2. Synthesis and complexation of bis (1-azaazulen-2-yl)-amines and bis(1-azaazulen-2yl)sulfides
Eiko Yoshioka, Kazuya Koizumi, Kenji Nakashima, Hiroyuki Fujii, Toshihiro Murafuji, Takahiro Gunji, and Noritaka Abe*
Heterocycles 2012, 85, 1683-1695
1. Unexpected formation of stannolanes and trigonal bipyramidal tin complexes by radical cyclization reaction
Akio Kamimura*, Shingo Ishikawa, Fumiaki Noguchi, Takaaki Miriyama, Masahiro So, Toshihiro Murafuji, Hidemitsu Uno
Chem. Commun. 2012, 48, 6592-6594.
川本拓治
2. Radical Addition of Alkyl Halides to Formaldehyde in the Presence of Cyanoborohydride as a Radical Mediator. A New Protocol for Hydroxymethylation Reaction,
Kawamoto, T.; Fukuyama, T.; Ryu, I.,
J. Am. Chem. Soc. 2012, 134, 875-877. - Highlighted in Synform, 2012, 5. - Highlighted in Nachrichten aus der Chemie, 2012, 60, 210.
1. Free Radical-mediated Hydroxymethylation Using CO and HCHO
Kawamoto, T.; Ryu, I.
Chimia 2012, 66, 372-376.
